Physical Chemistry, 5/e (Paperback)

KEITH J. LAIDLER , EmeritusJOHN H. MEISER , BRYAN C. SANCTUARY

  • 出版商: Multi-Media Publicat
  • 出版日期: 2019-10-01
  • 定價: $1,280
  • 售價: 9.5$1,216
  • 語言: 英文
  • 頁數: 1088
  • ISBN: 986769628X
  • ISBN-13: 9789867696281
  • 相關分類: 化學 Chemistry
  • 立即出貨 (庫存=1)

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商品描述

本書序言

In this fourth edition of our book we have preserved much of the material of the former editions, making changes only to improve understanding of the concepts or include some of the latest discoveries in physical chemistry. Many chapters have new sections and the coverage of several chapters has been greatly expanded. Unfortunately, in order to save space, we had to delete Chapter 20, Macromolecules. Because of the importance of some ideas in that chapter to other areas of physical chemistry, we have, however, transferred that material to other appropriate chapters.
Most of the numerical values for fundamental properties had to be adjusted in the light of recent data. A major new addition to thermodynamic data has been made in Appendix D; in addition, a table of CODATA thermodynamic data has been added that includes values for 8°(298.15 K) - H°(O). The data in Appendix D relate to data at 1 bar pressure.
A number of new problems are included in the fourth edition, giving instructors ample choices for their students. The sets of problems cover a wide range of subject matter and difficulty. This new edition, as well as its accompanying Solutions Manual, has been thoroughly checked for accuracy.
With this edition, we are pleased to introduce a particularly useful way to visualize physical processes. The CD included with this text allows the student to utilize many interactive graphs of physical relationships. The user can ascertain the effect of changing a variable in what might be a complex relationship. In addition, many figures are animated and give a clear understanding of difficult concepts. Included dialogue, textual information, and text links give the student a well rounded way to learn.

本書特色

We have deliberately given a distinctive historical flavor to the book, in part because the history of the subject is of special interest to many students. More importantly, we are convinced that many scientific topics are more comprehensible if they are introduced with some regard to the way in which they originally came to be understood. For example, attempts to present the laws of thermodynamics as postulates are in our opinion unsatisfactory from the pedagogical point of view. A presentation in terms of how the laws of thermodynamics were deduced from the experimental evidence is, we think, much easier for students to understand. In addition, by seeing the historical development of a subject we learn more about the scientific method than we can learn in any other way.
We realize that an historical approach may be dubbed "old-fashioned," but fashion must surely give way to effectiveness. We have also included eleven short biographies of scientists, chosen not because we think their work more important than that rf others (for who is able to make such a judgment?), but because we find their lives and careers to be of particular interest.
Several special aids are provided for the student in this book. New to this edition is the Objectives section listing key ideas or techniques that the student should have mastered after finishing the chapter. The Preview of each chapter describes the material to be presented in a brief narrative that gives a sense of unity to the material of the chapter. All new terms are in italics or in boldface type. Particular attention should be paid to these terms as well as to the equations that are boxed for special emphasis. Key equations that appear in the chapter occur in a concise listing at the end of each chapter. The mathematical relationships provided in Appendix C should prove useful as a handy reference.

商品描述(中文翻譯)

本書序言

在本書的第四版中,我們保留了前幾版的大部分內容,僅進行了一些改動,以提高對概念的理解或包含一些最新的物理化學發現。許多章節都有新的部分,並且有幾個章節的內容得到了大幅擴展。不幸的是,為了節省空間,我們不得不刪除第20章,即大分子。然而,由於該章節中的一些思想對其他物理化學領域非常重要,我們已將該材料轉移到其他適當的章節中。
基本性質的大部分數值都必須根據最新數據進行調整。在附錄D中新增了重要的熱力學數據;此外,還添加了一個包含8°(298.15 K) - H°(O)數值的CODATA熱力學數據表。附錄D中的數據與1大氣壓下的數據相關。
第四版中包含了一些新問題,供教師為學生選擇。這些問題涵蓋了各種主題和難度。這個新版以及其附帶的《解答手冊》已經經過仔細檢查,確保準確性。
在這個版本中,我們很高興介紹一種特別有用的視覺化物理過程的方式。隨書附帶的CD允許學生使用許多交互式物理關係圖表。使用者可以確定改變變量對可能是複雜關係的影響。此外,許多圖表都是動畫的,可以清楚地理解困難的概念。包含對話、文字信息和文本鏈接的內容使學生能夠全面學習。

本書特色

我們故意為本書賦予了獨特的歷史風味,部分原因是因為科學主題的歷史對許多學生來說很有趣。更重要的是,我們相信,如果能以一些對原始理解方式的尊重來介紹科學主題,那麼許多科學主題將更易於理解。例如,我們認為將熱力學定律作為公理來呈現是不令人滿意的。從實驗證據推導熱力學定律的方式,我們認為對學生來說更容易理解。此外,通過了解一個主題的歷史發展,我們可以更多地了解科學方法,這是其他方式無法學到的。

我們意識到,歷史方法可能被稱為“老派”,但時尚肯定應該讓位於效果。我們還包括了十一位科學家的簡短傳記,這些科學家的選擇不是因為我們認為他們的工作比其他人更重要(誰能做出這樣的判斷?),而是因為我們覺得他們的生活和職業特別有趣。

本書為學生提供了幾種特殊的輔助工具。本版新增了“目標”部分,列出了學生在完成章節後應該掌握的關鍵思想或技巧。每章的預覽以簡短的敘述描述將要呈現的內容,給人一種統一的感覺。所有新術語都以斜體或粗體字顯示。應特別注意這些術語以及以方框標記的方程式。每章結束時,列出了出現在該章中的關鍵方程式的簡明列表。附錄C中提供的數學關係應該作為一個方便的參考工具。

作者簡介

KEITH J. LAIDLER - University of Ottawa
EmeritusJOHN H. MEISER - Ball State University
BRYAN C. SANCTUARY - McGill University

作者簡介(中文翻譯)

KEITH J. LAIDLER - 渥太華大學
Emeritus JOHN H. MEISER - 波爾州立大學
BRYAN C. SANCTUARY - 麥吉爾大學

目錄大綱

1 The Nature of Physical Chemistry and the Kinetic Theory of Gases
2 The First Law of Thermodynamics
3 The Second and Third Laws of Thermodynamics
4 Chemical Equilibrium
5 Phases and Solutions
6 Phase Equilibria
7 Solutions of Electrolytes
8 Electrochemical Cells
9 Chemical Kinetics I. The Basic Ideas
10 Chemical Kinetics II. Composite Mechanisms
11 Quantum Mechanics and Atomic Structure
12 The Chemical Bond
13 Foundations of Chemical Spectroscopy
14 Some Modern Applications of Spectroscopy
15 Statistical Mechanics
16 The Solid State
17 The Liquid State
18 Surface Chemistry and Colloids
19 Transport Properties
Appendix A Units, Quantities, and Symbols: The SI/IUPAC Recommendations
Appendix B Physical Constants
Appendix C Some Mathematical Relationships
Appendix D Standard Enthalpies, Entropies, and Gibbs Energies of Formation
Appendix E Character Tables for Some Important Symmetry Groups in Chemistry
Answers to Problems

目錄大綱(中文翻譯)

1. 物理化學的性質和氣體動力學理論
2. 熱力學第一定律
3. 熱力學第二和第三定律
4. 化學平衡
5. 相和溶液
6. 相平衡
7. 電解質溶液
8. 電化學電池
9. 化學動力學I. 基本概念
10. 化學動力學II. 複合機制
11. 量子力學和原子結構
12. 化學鍵
13. 化學光譜學基礎
14. 光譜學的一些現代應用
15. 統計力學
16. 固態
17. 液態
18. 表面化學和膠體
19. 傳輸性質
附錄A 單位、量和符號:SI/IUPAC建議
附錄B 物理常數
附錄C 一些數學關係
附錄D 標準生成焓、熵和吉布斯能
附錄E 化學中一些重要對稱群的特徵表
問題的答案