Modulation Strategies of Cu-Based Electrocatalysts for Enhancing Electrocatalytic CO2 Conversion
暫譯: 基於銅的電催化劑調變策略以增強電催化二氧化碳轉換

Wang, Lei, Tan, Zhongchao, Wu, Yimin

Modulation Strategies of Cu-Based Electrocatalysts for Enhancing Electrocatalytic CO2 Conversion
  • 出版商: Springer
  • 出版日期: 2025-07-08
  • 售價: $5,110
  • 貴賓價: 9.5 折 $4,855
  • 語言: 英文
  • 頁數: 158
  • 裝訂: Hardcover - also called cloth, retail trade, or trade
  • ISBN: 3031980557
  • ISBN-13: 9783031980558
  • 相關分類: 材料科學 Meterials

    • 海外代購書籍(需單獨結帳)

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商品描述

The electrocatalytic reduction of CO₂ into high-value multi-carbon products represents a crucial pathway toward achieving carbon neutrality and sustainable chemical production. The transition from lab-scale studies to industrial-scale implementation is imperative to bridge the gap between fundamental mechanistic insights and practical applications.

This book explores the mechanistic understanding and functional design of electrocatalysts for CO₂ electroreduction, focusing on bridging the gap between lab-scale research and industrial-scale implementation. It systematically investigates the role of grain boundary structures, oxidation states, and interfacial microenvironments in stabilizing Cu-based catalysts, thereby enhancing the selective production of multi-carbon products. By integrating oxidation and alloying strategies, this work introduces new approaches to modulate copper oxidation states, leading to improved catalytic performance. Advanced characterization techniques, including in situ multimodal spectroscopy, provide insights into the electrochemical stability of Cuδ⁺ species and their impact on reaction pathways.

Beyond catalyst design, this book extends the discussion to CO₂ electrolyzer configurations, emphasizing membrane electrode assemblies and gas diffusion electrode engineering for scalable applications. The introduction of functionalized carbon black to modulate the interfacial environment, effectively suppresses the hydrogen evolution reaction, stabilizing active Cuδ⁺ species and promoting ethylene production with high Faradaic efficiency.

By integrating fundamental insights with industrial feasibility, this book offers a comprehensive guide for researchers and engineers developing next-generation CO₂ electrolysis technologies, contributing to carbon-neutral chemical manufacturing and sustainable energy solutions.

商品描述(中文翻譯)

二氧化碳（CO₂）的電催化還原為高價值的多碳產品，代表著實現碳中和和可持續化學生產的重要途徑。從實驗室規模的研究過渡到工業規模的實施是彌合基礎機制洞察與實際應用之間差距的關鍵。

本書探討了CO₂電還原的電催化劑的機制理解和功能設計，重點在於彌合實驗室規模研究與工業規模實施之間的差距。它系統性地研究了晶界結構、氧化態和界面微環境在穩定基於銅的催化劑中的作用，從而增強多碳產品的選擇性生產。通過整合氧化和合金化策略，本研究引入了調節銅氧化態的新方法，從而改善催化性能。先進的表徵技術，包括原位多模態光譜，提供了對Cuδ4物種的電化學穩定性及其對反應途徑影響的見解。

除了催化劑設計，本書還擴展了對CO₂電解槽配置的討論，強調膜電極組件和氣體擴散電極工程在可擴展應用中的重要性。引入功能化的炭黑以調節界面環境，有效抑制氫氣演化反應，穩定活性Cuδ4物種，並促進高法拉第效率的乙烯生產。

通過將基礎見解與工業可行性相結合，本書為研究人員和工程師提供了一本全面的指南，幫助他們開發下一代CO₂電解技術，為碳中和化學製造和可持續能源解決方案做出貢獻。

作者簡介

Lei Wang is a PhD student at the University of Waterloo, Canada. He received his BSc and MSc degrees from Hefei University of Technology, China, and University of Science and Technology of China, China, respectively. Lei's research interests are in design and optimization of membrane electrode assembly reactors for industrial-grade applications.

Dr. Zhongchao Tan is a Fellow of the Canadian Academy of Engineering. He is a Founding Chair Professor and Vice Provost & Dean of Academic Affairs at the Eastern Institute of Technology, Ningbo, China. He received his BSc and MSc degrees from Tsinghua University, Beijing, and PhD from the University of Illinois, Urbana-Champaign, USA in 2004. He was the founding Executive Director of Tsinghua-Waterloo Joint Research Centre for Energy and Environmental Technologies, and the Associate Dean (International) of Waterloo Engineering. In addition, Tan has provided dedicated services to several professional societies, including the Canadian Society for Mechanical Engineering, Canadian Society of Chemical Engineering, International Association for Green Energy, Standard Council Canada/ISO, and the Canadian Academy of Engineering.

Dr. Yimin Wu is the inaugural Tang Family Chair in New Energy Materials and Sustainability and a professor at the Department of Mechanical and Mechatronics Engineering, Waterloo Institute for Nanotechnology, University of Waterloo, Canada. Professor Wu's research focuses on the design of new energy materials for solar fuels and batteries, and novel electronic, photonic, responsive materials for flexible electronics and soft robotics, and energy efficient neuromorphic computing through a deep understanding of energy transduction processes at interfaces. Dr Wu is the director of the Materials Interfaces Foundry (MIF) at the University of Waterloo and serves on the board of directors of the Waterloo Institute for Nanotechnology and serves on the editorial board of the journal Energy and Environmental Materials. Dr Wu has authored and co-authored more than 100 peer-reviewed journal papers, which includes Nature, Nature Energy, Nature communications, and Advanced Materials. He is listed as an inventor on 7 US/international patents and has delivered over 40 invited lectures across the world in last 5 years.

作者簡介(中文翻譯)

王雷是加拿大滑鐵盧大學的博士生。他分別在中國合肥工業大學和中國科學技術大學獲得了學士和碩士學位。王雷的研究興趣在於設計和優化工業級應用的膜電極組合反應器。

譚仲超博士是加拿大工程學院的院士。他是中國寧波東方科技學院的創始講座教授及學術事務副校長和院長。他於2004年在北京清華大學獲得學士和碩士學位，並在美國伊利諾伊大學香檳分校獲得博士學位。他曾擔任清華-滑鐵盧能源與環境技術聯合研究中心的創始執行主任，以及滑鐵盧工程學院的國際副院長。此外，譚博士還為多個專業學會提供了專業服務，包括加拿大機械工程學會、加拿大化學工程學會、國際綠色能源協會、加拿大標準協會/ISO，以及加拿大工程學院。

吳怡敏博士是新能量材料與可持續性唐氏家族講座的首任教授，並在加拿大滑鐵盧大學機械與機電工程系及滑鐵盧奈米技術研究所任教。吳教授的研究專注於設計用於太陽燃料和電池的新能量材料，以及用於柔性電子和軟體機器人的新型電子、光子、響應材料，並通過深入理解界面上的能量轉換過程來實現能效神經形態計算。吳博士是滑鐵盧大學材料界面鑄造所（MIF）的主任，並在滑鐵盧奈米技術研究所的董事會任職，還擔任期刊《能源與環境材料》的編輯委員會成員。吳博士已發表和共同發表超過100篇同行評審的期刊論文，包括《自然》、《自然能源》、《自然通訊》和《先進材料》。他在7項美國/國際專利中被列為發明人，並在過去5年中在全球發表了超過40場受邀演講。

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